Beilstein J. Org. Chem.2012,8, 1528–1535, doi:10.3762/bjoc.8.173
ß-cyclodextrin in water. Via radical ring-opening copolymerization of 5 and NiPAAm a graft copolymer 8 with a clouding point of 32 °C was synthesized. The branched unsaturated polymer was treated with ozone to cleave the double bonds of the main chain.
Keywords: branchedpoly(NiPAAm); cloud point
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Graphical Abstract
Scheme 1:
Mechanism of free radical ring-opening polymerization of 2-VCPs (In: initiator) [29-31].